6/4/2023 0 Comments Lumo the mimeFe (II) also has a small gap between HOMO and LUMO, because it has 6 electrons in 3d orbitals. CO has a small gap between the HOMO and LUMO. Where possible, images are represented by thumbnails. The LUMO is a orbital that is also mostly on carbon, and it is kind of low-energy because the splitting of MOs is smaller than MOs (because of less overlap). The download button will force most browsers to prompt for a file name to store the data on your hard disk. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained. To open or display or play some files, you may need to set your browser up to use the appropriate software. Structure factor file (CIF format) (228.3 kbytes) Structure factor file (CIF format) (136.4 kbytes) Structure factor file (CIF format) (263.5 kbytes) Keywords: addition-elimination di-Schiff base synthesis characterization benzil dihydrazone crystal structure. triclinic (space group P ) for BDHPCB, monoclinic (space group P2 1/ n) for BDHOCB and orthorhombic (space group Pnna) for BDHMCB.įormula: C 28H 20Cl 2N 4, C 28H 20Cl 2N 4 and C 28H 20Cl 2N 4 The crystal systems are different, however, viz. the molecular structure and vibrational spectra of 1-methyl-2-imidazolethiol (MIME) were presented. For instance, they have the same chemical formula, all the molecules have a symmetrical double helix structure, with each Ph-C=N-N=C-Ph arm exhibiting an anti conformation, and their supramolecular interactions include intermolecular - and weak C-H stacking interactions. Request PDF Vibrational assignment, HOMO - LUMO. The structural features of the three new Schiff bases are similar. The compounds were characterized by single-crystal X-ray diffractometry, elemental analysis, melting point, 1H NMR and 13C NMR spectroscopy. the product is mainly governed by its stability. In the case of the systems studied, the type of Schiff base produced exhibits a clear dependence on the HOMO-LUMO energy gaps ( E HOMO-LUMO), i.e. Density functional theory (DFT) calculations were performed to explain the trend in the experimental results. Surprisingly, only di-Schiff bases were obtained our attempts to push the reaction in favour of the mono-Schiff bases all failed. TanĪbstract: A series of mono- and di-Schiff bases formed between benzil dihydrazone hydrazine (BDHOCB), and the 3-chloro (BDHMCB) and 4-chloro (BDHPCB) analogues, all having the formula C 28H 20Cl 2N 4. 803003) operated by Lumo at Edinburgh Waverley station, platform 10. C 71, 554-563 Experimental and theoretical studies of the products of addition-elimination reactions between benzil dihydrazone and three isomeric chlorobenzaldehydes Y.-N. Original file (4,000 × 3,000 pixels, file size: 1.96 MB, MIME type: image/jpeg).
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6/4/2023 0 Comments Flint knifeThis was done in March 1933 by Léon André, who worked mainly on consolidating the ensemble, and conserving the ivory handle. Boreux later proposed that the knife be restored, and that the blade and handle be joined together. Īt the time of purchase, its blade and handle were separated, as the seller did not realise that they fitted together. Similar portrait of a probable Uruk King-Priest with a brimmed round hat and large beard, excavated in Uruk and dated to 3300 BC. It is, in definitive, in tangible and summary form, the first chapter of the history of Egypt (emphasis in the original). You can judge the importance of this asiatic representation we will own one of the most important prehistoric monuments, if not more. At the top of the hunting scene the hunter wears a large Chaldean garment: he head is covered by a hat like that of our Gudea and he grasps two lions standing against him. On one side is a hunting scene on the other a scene of war or a raid. This is a work of great detail and the interest of what is represented extends even beyond the artistic value of the artefact. This is the masterpiece of predynastic sculpture executed with remarkable finesse and elegance. an archaic flint knife with an ivory handle of the greatest beauty. On 16 March 1914, he wrote to Charles Boreux, then head of the département des Antiquités égyptiennes of the Louvre, about the item the unsuspecting dealer had offered him. Bénédite immediately recognised the artefact's extraordinary state of preservation as well as its archaic date. The Gebel el-Arak knife was bought for the Louvre by the philologist and Egyptologist Georges Aaron Bénédite in February 1914 from a private antique dealer, M. At the time of its purchase, the knife handle was alleged by the seller to have been found at the site of Gebel el-Arak, but it is today believed to come from Abydos. The knife was purchased in 1914 in Cairo by Georges Aaron Bénédite for the Louvre, where it is now on display in the Sully wing, room 633. The Gebel el-Arak Knife, also Jebel el-Arak Knife, is an ivory and flint knife dating from the Naqada II period of Egyptian prehistory (3500-3200 BC), showing Mesopotamian influence. The Gebel el-Arak knife (back and front), on display at the Musée du Louvre.īought by Georges Aaron Bénédite in Cairo from antique dealer M. 6/4/2023 0 Comments Burly men at sea achievementsOther than that, just play through the story, reach 40,000 Gems, and complete challenges. You have to complete Gold on all challenges, but if you upgrade your skills throughout the game, you’ll have an easier time. What separates you and the platinum is your skill in this game. There are no missable trophies, and Marvel’s Spider-Man takes longer because you have to complete it on the hardest difficulty. All 124 trophies are super easy to get it just takes a while. The original edition of Marvel’s Spider-Man has 74 (51 for platinum) trophies, and Miles Morales has 50. Marvel’s Spider-Man and Miles Morales (PS4) (PS5) The other trophies are for easy-to-finish challenges. Half of the gold trophies are obtainable by beating each level’s to-do list, while the other half asks you to complete each level in under six minutes. Untitled Goose GameĪ fun game that lets you take control of a goose wreaking havoc on a small town. If you follow a guide, you’ll find all missable power-ups and get the platinums. The high difficulty comes from specific bosses and the missable trophies, which are collector-specific. God of War Saga includes five full God of War games: I, II, III, Chains of Olympus, and Ghost of Sparta. All you need to do is reach a score of 16,000 to unlock all the trophies, which can be done by running up against the left-side red building. If you have each version, you can get three platinums in under an hour. Road Bustle stacks three times: EU, NA, AS. From there, all you need to do is reach level 23 and buy the tanks in the correct order to avoid a trophy glitch. Of Tanks and Demons III (PS4)Ī lot of trophy hunters will use a code (Up, Up, Down, Down, Up, Up, Right, Left, Left, Right Square) at the title screen after selecting a New Game to activate God Mode. It will take you three playthroughs to platinum this game, and you can get the majority of the trophies playing classic mode, arena mode, and hard mode. This 30-minute platinum can stack six times, one for vita, one for PS4, and four times for VITA and PS4 in the EU and Asia versions. It has simple to complete challenges, like dying five times, rescuing 33 Orbees, completing zone 5 while touching the floor buttons, and stepping on a single switch. BFF or Die (PS4)Ī super simple game that only takes 30 minutes to platinum most trophy hunters complete this game without meaning to. Start the game in hard mode from the select screen to get every trophy in one run. Terminator: Salvation (PS3)Īn incredibly dull but easy to platinum game with one missable trophy, Terminator: Salvation has nine trophies that require you to beat levels on any difficulty, while the other two are difficulty related. None of these trophies are difficult or missable. On level 1, beat it without dying, and on levels 3, 6, 9, and 10, beat the boss without dying. There are ten levels, and most can be completed in 30 minutes. Play solo when getting your trophies, as the co-op player won’t net you anything. This point-and-click adventure game is fun in its own right, and the trophies make you do mundane things like close the blinds ten times or ask for a solution to a puzzle. The Little Acre (PS4)Īlthough 12 of its 28 trophies are missable, you’ll have an easy two hour platinum if you follow a guide. Here are 50 games you can play to fill out your trophy list. I consider the following games the peak of trophy hunting, not due to their difficulty, but how fun they can be to complete. Most of the games on this trophy list are easy to beat or take less than ten hours to obtain. Not only can trophy hunting be fun, but it can also give you that hit of serotonin you need to keep playing the most complex games. Trophy hunting is like playing a game within a game. These achievements are proof of a player’s perseverance, diligence, and dedication when tackling challenges that are often separate from the games themselves. All genres 2.Platinum trophies are no small deal to a completionist, even if it takes less than an hour to get them. 6/4/2023 0 Comments Arc raiders free to playIn that statistical category, anything below 100 is considered above average so the fact that Washington met that standard in his first year at the Big 12 level is a great sign when it comes to what he could become on that end of the floor. When it came to his defensive rating (an estimation of the number of points a player allows the person he is guarding to score per every 100 possessions) Washington was third on the team at 99.3. That has to be appealing to McCasland, who is a defensive-minded head coach. On the other hand, the physical guard did prove to be a willing and capable defender. By contrast, senior point guard De’Vion Harmon, who had the ball in his hands far more than Washington did, averaged only 2.3 turnovers per 40 minutes. To put his turnover troubles in perspective, consider that Washington led the team in turnovers per 40 minutes played at 3.7. That included a woeful six-turnover game in only 20 minutes of action in the loss at Oklahoma State. Last season, he was often a walking turnover as on six occasions he gave the ball away three times or more. Perhaps even more important, though, might be his ability to learn how to take care of the ball more effectively. If he is going to become a valuable guard on a Big 12 contender, that aspect of his game must show significant improvement. Only a 23% shooter from 3-point range, he hit just 7 of 30 attempts from behind the arc in 2022-23. Specifically, he has to develop some semblance of a reliable jump shot. Still, Washington must improve his offensive game. 12 Kansas State Wildcats 71-63 in Lubbock. Similarly, in mid-February, he chipped in 13 points, 2 rebounds, and 5 assists as Tech stunned the No. His most memorable outing came against Nicholls in December when he went 12-17 from the free throw line to account for all of his points as he helped his team narrowly escape a massive home upset. For instance, he scored in double digits only twice, and on nine occasions in league play, he failed to register a point. Putting up 3.4 points, 1.8 rebounds, and 1.8 assists per game, he showed flashes of promise but he lacked the type of consistency that many wanted to see from him. Run it back, Year 2!!!❤️□ #Uno /smLnyg2Od5 That’s been an important part of new Texas Tech basketball head coach Grant McCasland’s agenda since he was hired last month and that process is still ongoing even amid the buzz surrounding the transfer portal.Īlready having secured the returns of guard Pop Isaacs and forward Robert Jennings while seeing players such as Jaylon Tyson, Fardaws Aimaq, Elijah Fisher, and Daniel Batcho find new homes via the portal, the new Red Raider coaching staff got good news this week when sophomore guard Lamar Washington announced on Wednesday that he will, in fact, stay in Lubbock for next season.Īn Oregon native who was largely recruited to Tech by former assistant coach Barrett Peery (who was sent packing by Mark Adams last offseason, before Washington ever even suited up for the Red Raiders), the 6-foot-4 guard was a hit-or-miss proposition as a true freshman.Īppearing in 32 games, Washington was 7th on last season’s team in minutes played averaging 15.2 per contest. Come prepared and plan ahead, but remember that sometimes you just have to wing it.Ĭheck out the gameplay-packed reveal trailer below.One of the more overlooked tasks that a new coaching staff must undergo in the process of putting together their initial roster is evaluating the players already in the program and deciding which to re-recruit. And further to that, do the unexpected and improvise, using physics and your surroundings to your advantage. It’s also a game in which you’ll be able to loot your fallen foes, and scavenge the ruins of the past for tools and gadgets to outsmart the enemy. It’s a game that both emphasizes and rewards teamwork at every turn. We look forward to sharing more about the game in the coming months.”ĭefeating ARC requires more than simply pointing and shooting a gun, and more than one person trying to be a hero. Ultimately for a co-op action game like ARC Raiders, that’s what matters the most. “With this reveal, we want to celebrate gameplay and give players more than a hint of how ARC Raiders looks and what it feels like to play. Today, that canvas is a lot less blank and those ideas are becoming realities,” said Patrick Söderlund, co-founder and CEO of Embark Studios. “We started Embark Studios three years ago with a blank canvas and some big ideas. ARC Raiders will be free to play and is planned for a 2022 release on the Xbox Series X|S, PS5 and PC through the Epic Games Store, Steam and Nvidia GeForce NOW’s game streaming service He carries a gun in each hand like a boss. However Ugh-Zan uses his hands for more important business's, like slapping his biatches or driving his pimped-out alien ride. He comes from the planet of Pimp-Zania and like the reptiloids he as well has four arms. The Vicious Warlock-Pimp - Just as his name suggests Ugh-Zan is a Vicious Warlock-Pimp. Ugh-Zan The Vicious Warlock-Pimp shaking his fists of fury! Ugh-Zan III Due to their many hands they are quite efficient at what they do. Reptiloids are 4-armed crack addicts that give hand jobs for a fix. Sam can always count on his trusted Werebull to be there wether he needs to travel countless miles or ride into battle. The Gnaar are vicious one-eyed monsters who have a single purpose: To bite, bite, bite, bite, bite, bite, bite and bite everything they encounter. The Kleer are Sam's closest companions and they follow him around wherever he goes and aid him in any way they can. The Kleer are the skeletal remains of the actors that starred in Clerks. NETRICSA contains information about the various items and beings Sam encounters in his journey. NETRICSA is some high-tech nano-encyclopedia-device implanted in Sam's brain. However being the serious badass that he is, Sam chooses to rebel by killing off thousands upon thousands of Mental's troops. This would mean that Sam himself is a less ancient immortal God going through his teenage phase in which he, as any other teenager, rebells against his parents. Mental also happens to be Sam's archenemy and some say even father. On the bright side this leaves You pretty much safe. 6/3/2023 0 Comments Road tripper england
6/3/2023 0 Comments Keep it simple aa big bookI believe that all sacrifice and all suffering is of value to me. Do I have real fellowship with other people and with God? A sober life is a happy life, because by giving up drinking we’ve got rid of our loneliness and remorse. When you come into A.A., you begin to get right with other people and with God. As a result, you have that terrible remorse. You know you’re not living the way God wants you to. No matter how you were brought up, no matter what your religion is, no matter if you say you believe in God, nevertheless you build up a wall between you and God by your drinking. Or Follow Us On Twitter #essentialsofrecoveryĭrinking cuts you off from God. Why not sign up to get emails with all daily posts included? The more one analyzes the Lord’s Prayer, the more wonderful its construction is seen to be.Īfter that manner therefore pray ye. The seven clauses are put together with the utmost care, in perfect order and sequence, and they contain everything that is necessary for the nourishment of the soul. Seven symbolizes individual completeness, the perfection of the soul, just as the number twelve in the same convention stands for corporate completeness. This is very characteristic of the Oriental tradition. The first thing that we notice is that the Prayer naturally falls into seven clauses. The mere acquisition of fresh knowledge received intellectually makes no change in the soul. It is designed with the utmost care for the specific purpose so that those who use it regularly, with understanding, will experience a real change of soul. The Great Prayer is a compact formula for the development of the soul. Everyone who is seeking to follow along the Way that Jesus led, should pray the Lord’s prayer intelligently every day. The Lord’s Prayer is the most important of all the Christian documents. “Some of us have tried to hold on to our old ideas and the result was nil until we let go absolutely.” “We, who have traveled this dubious path, beg you to lay aside prejudice, even against organized religion.” Sometimes this was a tedious process: we hope no one else will be prejudiced for as long as some of us were.” “Besides a seeming inability to accept much on faith, we often found ourselves handicapped by obstinacy, sensitiveness, and unreasoning prejudice.” “It finally beat us into a state of reasonableness. “Do not let any prejudice you may have against spiritual terms deter you from honestly asking yourself what they mean to you.” “We found that as soon as we were able to lay aside prejudice and express even a willingness to believe in a power greater than ourselves, we commenced to get results, even though it was impossible for any of us to fully define or comprehend that power, which is God.” “It meant I would have to throw several lifelong conceptions out of the window.” “God, please set aside everything I think I know about myself, the twelve steps, this book, the meetings, my disease, and you, God, so I may have an open mind and a new experience with all these things, please let me see the truth.”Īlthough the set aside prayer that we use is not found as we say it in the Big Book of “Alcoholics Anonymous” here are some references to it: My maternal grandmother, herself a deeply religious woman who lived with us, helped raise me and was a living example of unconditional love.īIG BOOK - Alcoholics Anonymous - HE LIVED ONLY TO DRINK - p. There was caring and togetherness among us. They were both champions of community outreach and well respected. My parents were also educators my father was principal of the school I attended, and my mother taught there. My father was a minister, and I attended his church every Sunday with the rest of the family and, like them, was very active in religious work. We were from a long Southern Missionary Baptist tradition. To our collective memory there was no drinking on either side of the family. On looking back at my life, I can’t see anything that would have warned me or my family of the devastation that alcoholism had in store for us. It happened to me and this is what I did about it.'” “I had been preached to, analyzed, cursed, and counseled, but no one had ever said, ‘I identify with what’s going on with you. 6/3/2023 0 Comments Audio hijackTo immediately start working with Audio Hijack 3, click the “New Session” button at bottom-left. But before we get off doing that, let’s first see what you can do with Audio Hijack 3 beyond recording audio, as well as what you would probably like to install first.Īudio Hijack lets you record audio from a mixture of devices, including microphones, DVD players, ADC’s (Analogue to Digital Converters - these are the devices that convert analogue signals into digital data. When you first start up the app, you’ll be greeted with an empty Home window. This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.In this Audio Hijack 3 tutorial I’ll be taking you through the entire app right from when it has been installed on your system. Leanpub is copyright © 2010-2023 Ruboss Technology Corp. Batch convert nearly any audio file to MP3, AAC, Apple Lossless, FLAC, AIFF, or WAV format.Lastly, you’ll learn how to use Fission to polish your recordings. If you transcribe live broadcasts, time shifting is a major productivity booster! It’s also great for enabling restroom breaks during a live streaming radio show. Even though it’s live, you want to pause and resume, or go back a few seconds or jump ahead (if there’s anything to jump ahead to). If you’ve ever used a TiVo, you know what this means: You’re listening to a live stream, but you can’t pay attention continuously. Time shifting live audio while you listen.For example, Rdio might not be able to use AirPlay to send music to your AirPort Express, but Audio Hijack can. Piping audio around your house while you listen in creative ways.For example, your little laptop’s speakers might not provide enough oomph for an action thriller’s soundtrack, but with Audio Hijack you can boost that sound and enjoy the flick. Enhancing audio while you listen to it.If you’re interested in enhancing your aural experience, you’ll find help with: Finding your recordings in Audio Hijack and the Finder.Recording to multiple files and formats.Breaking a digitized album into separate songs.Digitizing an LP or cassette, while reducing hiss and noise.Ducking one audio source when a second source kicks in.Checking volume levels before you record.Capturing a chat from Skype, FaceTime, and other voice-over-IP apps.Scheduling when your Mac should record something automatically.Setting up reusable sessions with Audio Hijack’s Audio Grid interface.Recording literally any audio played on your Mac.This book was created in collaboration with Rogue Amoeba, who worked with us to make this book more accurate, more detailed, and just plain better.Īs far as recording goes, you’ll find help with: It also explains how to turn an audio file into a ringtone and - podcasters and educators take note! - how to make a chapterized AAC file. The Fission chapter has directions for trimming, cropping, adding, replacing, splitting, combining, and fading audio. You’ll also discover special features such as reusable sessions, recording to more than one file (and format) at once, scheduling recordings, time shifting during live playback, effects like ducking and panning, adding automatic metadata before recording, and more. For example, by boosting the volume or tweaking the bass - movies on Netflix never sounded better! You’ll learn how to pipe sound through Audio Hijack to enhance its quality without recording. Kirk also helps you edit recordings in Rogue Amoeba’s Fission audio editor. Audio expert Kirk McElhearn provides instructions for setting up common scenarios - recording audio playing in Safari, capturing Skype and FaceTime calls, digitizing your old LPs, extracting audio from concert DVDs, and working with mics and mixers, among much else. Learn how to use Rogue Amoeba’s Audio Hijack 3 to capture and enhance any audio playing on a Mac. As WhatsApp messages are synced between the two phones instantly, any chats you delete on the primary device are also deleted on the secondary device, or vice-versa. As for general usage, the secondary device works quite well, without any perceivable delay when sending or receiving messages. For those wanting read receipts, WhatsApp’s companion mode provides that too. Users can even set a custom last seen and online status, profile photo, and “About” visibility, as they would on the primary device. Furthermore, disappearing messages in chats also carry over to secondary devices for greater privacy. For starters, the much-used biometric lock feature is available on companion devices, allowing users to lock access to their WhatsApp chats. Step 5: WhatsApp Features on Secondary DeviceĮven though you might think the secondary device on WhatsApp might be barebones, it carries over some of the original features from the primary device. Do remember that iOS as a secondary device isn’t supported just yet. The Samsung C24FG73 sports a 24-inch curved VA panel with a 1920 x 1080 resolution, 144Hz refresh rate, and 1ms response time. That means, even if you lose internet access on your primary device, you will be able to use WhatsApp on your secondary device without hiccups.Īnd that’s how easy it is! You can repeat the above steps anytime with other devices, be it Android or iOS, to get WhatsApp’s Companion Mode working. You can now use them without any issues whatsoever, and they will work like independent devices. You will now see WhatsApp on both your primary and secondary devices. Once done, tap on “ Agree and continue” to move to the login screen. On the first screen, choose your language and tap the arrow to proceed. Step 1: Install WhatsApp on the Secondary Deviceįirst, you need to install WhatsApp (Free, Android and iOS) on your secondary phone. Also, Android tablets support the new companion mode as well. It’s expected that secondary device support for iOS will roll out in due time. Note: The WhatsApp Companion Mode only supports the second device is an Android right now, and you cannot use an iOS device as the secondary device as of writing this guide. How to Use the Same WhatsApp Account on Multiple Phones So follow the steps below as we show you how to use your main WhatsApp account on two different phones – be it Android or iPhone. WhatsApp’s previously limited testing Companion Mode is now available to all Android and iOS users. While initially there was no official way to use the same WhatsApp account on two phones, that has now changed. Run the game setup inside the extracted folder and install the game.Once SPORE: Galactic Adventures has finished downloading, extract the file using a software such as WinRAR.If using a torrent download, you will first need to download uTorrent. Choose a mirror to complete your download.You will be redirected to a download page for SPORE: Galactic Adventures. Important: You need to have the SPORE base game installed before you can download this expansion pack. How to Download and Install SPORE: Galactic Adventures In addition, fixed objects from the previous stages of Spore, as well as gameplay objects like bombs and teleporters, can be added to the game. The player can also set creatures’ behaviours from aggressive to friendly, and add speech bubbles. Creatures, vehicles and buildings created using the game’s other editors can be selected and placed throughout the world. Players add elements to the adventure by dragging them from a menu and dropping them into the world. This Creator allows players to create various missions, which are then populated into the Space stage in a manner similar to the other content created in the original game. Spore: Galactic Adventures is an expansion pack for the multi genre game Spore, developed by Maxis and published by Electronic Arts.The main feature added to the game is the Adventure Creator. Download SPORE: Galactic Adventures for free on PC – this page will show you how to download and install the full version of SPORE: Galactic Adventures on PC. |